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半-導體 Semi-conductor
導體(Conductor)是指可以輕鬆傳導電流的材料像是金屬
A conductor is a material which ”conductor" electricity easily (such as metals).
絕緣體(Insulator)是指幾乎沒有導電能力的材料像是玻璃
An insulator is a material which is a very poor conductor of electricity (such as glass)
半導體矽(硅)就像是絕緣體的材料,但當與其他材料結合時會有類似導體的行為
A semiconductor (such as silicon) is a material which acts like an insulator, but can behave like a conductor when it is combined with other materials.

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環境中的矽 (Si in the environment)

矽是地球上第二豐富的元素,僅次於氧
Silicon is the second-most abundant element on the planet, after oxygen.
矽約佔地殼的 25%
Silicon makes up about 25 percent of the Earth's crust.
矽具有良好的導熱性
Silicon has good thermal conductivity.

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元素週期表 (Periodic Table of Elements)

*轉載節錄自Wiki 
Reprinted and excerpted from Wiki
四族半導體:矽/鍺
IV semiconductors: Si/Ge
三五族半導體:由三族的鋁(Al)、鎵(Ga)、銦(In)及五族的氮(N)、磷(P)、砷(As)、銻(Sb)等等組成。由於是化合物,所以組成方式非常多種,有二元的 GaN、GaAs、InP;三元的 InGaAs、InGaP;甚至四元的 InAlGaAs 或 InGaAsP 
III-V semiconductors: Component by III Al/Ga/In and N/P/As/Sb. Because it is a compound, there are many ways of composition.There are binary GaN, GaAs, InP; ternary InGaAs, InGaP; even quaternary InAlGaAs or InGaAsP

 

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矽晶體結構 Silicon Crystalline Structure

晶體是由單個均勻陣列/結構中的原子組成的固體
A crystal is a solid composed of atoms in a single uniform array/structure.
每個矽原子與其最近的四個相鄰矽原子相連
Each silicon atom is connected to its four nearest neighboring silicon atoms.

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共價鍵(共享電子)Covalent Bond (Sharing Electron)

包括矽在內的許多原子的外軌道都喜歡有八個電子
Many atoms including silicon like to have eight electrons in their outer orbit.
矽只有四個外層電子
Silicon has only four outer electrons.
通過共享每個原子的 1 個電子,在兩個矽原子之間成鍵
Bonding between two Si atoms by sharing 1 electron from each atom.

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氮系矽化物鍵結示意圖 Bond Pictures of N-Type Silicon

砷與磷有五個共價電子
As and P have 5 valence electrons
1 個額外的電子可以穿過晶體
1 additional electron can move through the crystal

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磷系矽化物鍵結示意圖 Bond Pictures of P-Type Silicon

硼有三個共價電子
B has 3 valence electrons.
缺少 1 個電子的空缺可以穿過晶體
1 electron is missing, a hole can move through the crystal.

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